Preliminary Pages

TABLE OF CONTENTS

LIST OF FIGURES

LIST OF TABLES

1 Introduction

1.1 Motivation

1.2 Overview of Post-fire Analysis of Construction Materials

1.2.1 Early Fire Scene Analysis (until the 1950s)

1.2.2 Fire Science in the 1960s and later

1.2.3 Fire Investigation Today

2 Wood

2.1 Physical characteristics of wood

2.2 Response of wood to fire

2.2.1 Wood dehydration

2.2.2 Thermal degradation of wood, hemicellulose, and a -cellulose

2.2.3 Active pyrolysis of wood, hemicellulose, and a -cellulose

2.2.4 Thermal degradation of lignin

2.2.5 Active pyrolysis of lignin

2.3 Summary: a “task of awesome complexity”

2.4 How the Fire investigation community has used wood:

2.4.1 Surface patterns

2.4.2 Rate of charring

2.4.3 Using char lines of demarcation to interpret fire evidence

2.4.4 Using depth and rate to determine time of burn

2.5 Summary: wood is plentiful, traditional, but unreliable

2.6 Research

2.6.1 Motivation

2.6.2 Methodology

2.7 Experimental results

2.7.1 Charring rate

2.7.2 Variability in char rate: a closer look

2.7.3 Attempt to make a “map” of heat flux and exposure time for wood

2.7.4 Fissures

2.7.5 Scanning Electron Microscope (SEM)

2.8 Conclusions about wood

3 Concrete

3.1 Physical and thermal characteristics of concrete

3.1.1 Physical characteristics of concrete

3.1.2 Thermal conductivity of concrete

3.2 Response to fire

3.2.1 Spalling

3.2.1.1 Spalling as a result of vapor pressure

3.2.1.2 Spalling as a result of thermal expansion of aggregate

3.2.2 Chemically Bonded Water

3.2.3 Loss of Strength

3.2.4 Changes in Coloration

3.3 Complicating Factors

3.4 How the Fire Investigation Community has used Concrete

3.4.1 Spalling

3.4.2 Coloration Changes

3.5 Summary of concrete section

3.6 Experiments to expose concrete to well characterized fire exposures

3.6.1 Motivation

3.6.2 Methodology

3.6.3 Results

3.7 Conclusions about concrete as an indicator of heat flux exposure, time, and temperature.

4 Gypsum

4.1 Physical characteristics of gypsum

4.2 Response to fire

4.3 The fire investigation community’s use of gypsum

4.4 Experimental research on gypsum

4.4.1 Experimental approach

4.4.2 Experimental observations

4.5 Conclusions on gypsum

5 Comparison to the theory

5.1 Variables

5.2 The thin-slab problem and an approximate solution

5.3 When will a thermocouple first register heat?

5.4 A numerical method: a solution for gypsum

6 Conclusions and Future Research

6.1 Conclusion: use gypsum, not wood or concrete

6.2 Future research

7 Wood Appendix

7.1 Wood protocol

7.2 Photographic images of wood

7.2.1 Wood atlas

7.2.2 Pyrolysis zone width study

7.3 Data, measurements, and analysis

7.3.1 Listing of Data Samples

7.3.2 Graphs of composite wood behavior

7.3.3 Analysis: rate of charring

7.3.4 Determination of exposure time and heat flux

8 Concrete appendix

8.1 Concrete protocol

8.2 Microscopic Observations

8.3 Petrographic images of concrete

8.3.1 SEM Examination of a single sample

8.3.2 SEM images of heated concrete

8.4 Data measurement and analysis

8.4.1 Listing of data samples

9 Gypsum Appendix

9.1 Gypsum protocol

9.2 List of gypsum samples and test conditions

9.3 Data, measurements, and analysis

9.3.1 Graphs of gypsum’s response to heat

9.3.2 Analysis: rate of isotherm progression

9.3.3 Determination of exposure time and heat flux

9.3.4 XRD Peaks Analysis