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          1We use “science” here to refer to a discipline with fixed metrics, measurable quantities, and satisfactory (if evolving!) theories to explain it. We use “art” to refer to all other situations, including one in which the metrics are not agreed upon or fixed, the meanings of different quantities are not mapped or understood, and no overriding unifying theory exists.

 

 

          2Compartment flashover is when the involved compartment becomes so hot that all exposed combustible surfaces spontaneously ignite. An investigator facing a compartment flashover fire would see sustained thermal damage on all exposed surfaces, making it difficult to determine which surfaces had been initially involved. A pre-flashover fire is generally localized, but after the compartment has been “fully involved” in the post-flashover period, the fire has generally destroyed the traces of the original source of fire.

 

 

          3Quotation is from [20], quoted by [21, p. 2].

 

 

          4The 300° C isotherm was identified as the “edge of the char frontier” by [30].

 

 

          5As quoted by [21].

 

 

          6It should be recognized that this thickness is contrary to that proffered by Roberts [22], DeHaan [38], and NFPA 921 [39] as discussed above.

 

 

          7There is no mention made here of other factors which may affect char patterns, such as wood species, ring orientation, relative size of the “lands,” or area surveyed for the relative size of the lands and cracking.

 

 

          8For the purpose of this dissertation, the use of “industry standard” will mean 0.635 mm/min or 1 inch/40 minutes.

 

 

          9Lawson’s original equation was given as V = 0.041t inches/minute,where V = rate of charring in inches per minute and t = time in minutes. The equation given in the text above has been converted to metric units.

 

 

          10Wood species can influence the density and moisture content as well.

 

 

          11For an uncontrolled fire.

 

 

          12For the research conducted here, we split a wood slab into different, parallel zones. Zone 0 is the zone from 0-4 mm from the exposed surface. Zone 1 is the region which is 4-12 mm from the exposed surface. And Zone 2 is the region which is 12-24 mm from the exposed surface. The junctions between the zones correspond to the thermocouple locations.

 

 

          13Oxygen consumption, rate of heat release and CO generation measurements derived through the use of the cone were acquired during testing but were considered secondary and not the focus of this research.

 

 

          14Note the original surface may no longer be available. The protocol to use is described in item 8.2 of the Wood Protocol (Section 7.1).

 

 

          15Slight variation may have been seen in the maple wood specimens; however, the data was insufficient to draw conclusive results.

 

 

          16In the hcp, the capillary pore size may range between 10 and 100 nanometers. The average aggregate is 10 micrometers.

 

 

          17“Well-aged” concrete is defined as that which has been “cured many months in a humid atmosphere.” [79, p. 29]

 

 

          18Common chemistry notations are used: C = CaO; S = SiO2; A = Al2O3; H = H2O.

 

 

          19The data from Zoldners [74] was cited by Neville [69].

 

 

          20Not all researchers agree on this point. See Short [101] for a paper which determines pink is not due to iron oxide.

 

 

          21Midkiff [86;104], citing B. Kennedy, found that gasoline penetrated into concrete at a rate of one inch per hour, but he does not discuss the physical attributes of the concrete from which this penetration rate was derived.

 

 

          22Pun not intended!

 

 

          23ACI 211.1 Standard, Recommended Practice for Selecting Proportions for Normal Weight Concrete.

 

 

          24The compression strengths were measurably lower then the theoretical strengths. This can be attributed to the failure to remove the plastic cylinder forms from the specimens until the day of testing. This inhibited the rate of curing and thus the measured 28-day strength. This would not have affected the strength of the cone calorimeter specimens since they were not cured in plastic containers.

 

 

          25See the description in the wood section for details; the calorimeter used is the same. (Section 2.6.2)

 

 

          26Found in the Appendix.

 

 

          27In particular, there was no difference in physical characteristics on a macro scale between specimens with no fibers, specimens with polymer fibers, and specimens with steel fibers.

 

 

          28Again, for a complete description of the calorimeter, see the wood section for details. (Section 2.6.2)

 

 

          29Timed insertion and cool down variables can also be introduced.

 

 

          30The control specimen was from the same batch of wallboard as the subject specimens.

 

 

          31The analytic solution requires that the thermal diffusivity a remain constant as the temperature rises. This is a reasonable approximation for the wood and the concrete samples, but is not true for the gypsum. The a for the gypsum varies widely as a function of the different crystal structures which occur at different temperatures.

 

 

          32See the explanation in Footnote 30.

 

 

          33Note that all the problems are one dimensional, so a measure of x alone will suffice. The y and z dimensions are not necessary.

 

 

          34Within certain bounds.

 

 

          35Recall the clean analytic solution presented in Section 5.2 was only an approximation of the thin-slab with a semi-infinite slab.

 

 

          36Note in the Sample ID, an “X” (as in 1OX_1) indicates a radial end-grain exposure. An “L” (as in 1OL_1) indicates a transverse (longitudinal) exposure.

 

 

          37Char depth was determined as per item 8 of the Wood Protocol in 7.1.

 

 

          38Note in the Sample ID, an “X” (as in 1OX_1) indicates a radial end-grain exposure. An “L” (as in 1OL_1) indicates a transverse (longitudinal) exposure.

 

 

          39The zones were defined in Section 2.7.1, which begins on page 29.

 

 

          40Pyrolysis is taken as 280° C.

 

 

          41Samples which were exposed for 4500 seconds are denoted with an asterisk (*). All other samples were exposed for 1500 seconds.

 

 

          42Zone 0 is 0-4 mm from exposed surface.

 

 

          43Zone 1 is 4-12 mm from exposed surface.

 

 

          44Zone 2 is 12-24 mm from exposed surface.

 

 

          45Samples which were exposed for 4500 seconds are denoted with an asterisk (*). All other samples were exposed for 1500 seconds.

 

 

          46Effective strength is expressed as a percentage of the theoretical maximum strength. For example, if a sample was supposed to have a strength of 21 Mpa,, but only measured at 10.5 Mpa,, its effective strength would be measured as 50%.

 

 

          47Recall that Zone 0 was between 0 and 4 mm from the exposed surface. Zone 1 was the region 4-12 mm from the exposed surface. Zone 2 was the region 12-24 mm from the exposed surface for the 24 mm (1 inch) gypsum; the region 12-16 mm from the exposed surface for the 16-mm gypsum. Because of the difference in gypsum widths, Zone 0 and Zone 1 were more heavily relied upon.

 

 

          48Hemihydrate is taken to be 80° C.

 

 

          49Insoluble b -CaSO4 is taken to be 200° C.

 

 

          50Anhydrous is taken to be at 500° C, which is also the temperature at which compartment flashover occurs.

 

 

          51Hemihydrate isotherm is at 80° C.

 

 

          52Zone 0 is 0-4 mm from exposed surface.

 

 

          53Rate calculation represents distance traveled (in mm) divided by time (in seconds).

 

 

          54Insoluble b -CaSO4 isotherm is at 200° C

 

 

          55Anhydrous isotherm is at 500° C. This is also the compartment flashover temperature.

 

 

          56Zone 1 is 4-12 mm from exposed surface.

 

 

          57Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.

 

 

          58Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.

 

 

          59N/A denotes data was not available.

 

 

          60Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.

 

 

          61Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.

 

 

          62Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.

 

 

          63Time is a prediction based upon the rates of isotherm progression calculated from the data observed by thermocouples.